Name: Assemblies of Gold Nanoparticles at Liquid-Liquid Interfaces: From Liquid Optics to Electrocatalysis (Springer Theses) (en Inglés)
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Author: Evgeny Smirnov

portada Assemblies of Gold Nanoparticles at Liquid-Liquid Interfaces: From Liquid Optics to Electrocatalysis (Springer Theses) (en Inglés)

Assemblies of Gold Nanoparticles at Liquid-Liquid Interfaces: From Liquid Optics to Electrocatalysis (Springer Theses) (en Inglés)

Formato

Libro Físico

Editorial

Springer

Autor

Evgeny Smirnov

Año

2019

Idioma

Inglés

N° páginas

280

Encuadernación

Tapa Blanda

ISBN13

9783030085728

Categorías

Química física

Assemblies of Gold Nanoparticles at Liquid-Liquid Interfaces: From Liquid Optics to Electrocatalysis (Springer Theses) (en Inglés)

Evgeny Smirnov (Autor) · Springer · Tapa Blanda

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Reseña del libro "Assemblies of Gold Nanoparticles at Liquid-Liquid Interfaces: From Liquid Optics to Electrocatalysis (Springer Theses) (en Inglés)"

This book is devoted to various aspects of self-assembly of gold nanoparticles at liquid-liquid interfaces and investigation of their properties. It covers primarily two large fields: (i) self-assembly of nanoparticles and optical properties of these assemblies; and (ii) the role of nanoparticles in redox electrocatalysis at liquid-liquid interfaces. The first part aroused from a long-lasting idea to manipulate adsorption of nanoparticles at liquid-liquid with an external electric field to form 'smart' mirrors and/or filters. Therefore, Chapters 3 to 5 are dedicated to explore fundamental aspects of charged nanoparticles self-assembly and to investigate optical properties (extinction and reflectance) in a through manner. Novel tetrathiafulvalene (TTF)-assisted method leads to self-assembly of nanoparticles into cm-scale nanofilms or, so-called, metal liquid-like droplets (MeLLDs) with remarkable optical properties. The second part (Chapters 6 to 8) clarifies the role of nanoparticles in interfacial electron transfer reactions. They demonstrate how nanoparticles are charged and discharged upon equilibration of Fermi levels with redox couples in solution and how it can be used to perform HER and ORR. Finally, Chapter 9 gives a perspective outlook, including applications of suggested methods in fast, one-step preparation of colloidosomes, SERS substrates as well as pioneer studies on so-called Marangony-type shutters drive by the electric field.