Name: Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles (en Inglés)
SKU: 57350719
Price: 160750.00 CLP
Availability: InStock
Author: Yoon, Hyung
ISBN: 9783030540760

portada Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles (en Inglés)

Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles (en Inglés)

Formato

Libro Físico

Autor

Hyung Yoon

Editorial

Springer

Idioma

Inglés

N° páginas

212

Encuadernación

Tapa Dura

Dimensiones

23.4x15.6x1.4 cm

Peso

0.52 kg.

ISBN13

9783030540760

Categorías

Química inorgánica
Química orgánica
Química industrial e ingeniería química

Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles (en Inglés)

Hyung Yoon (Autor) · Springer · Tapa Dura

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Reseña del libro "Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles (en Inglés)"

This book presents Pd- and Ni-catalyzed transformations generating functionalized heterocycles. Transition metal catalysis is at the forefront of synthetic organic chemistry since it offers new and powerful methods to forge carbon-carbon bonds in high atom- and step-economy. In Chapter 1, the author describes a Pd- and Ni-catalyzed cycloisomerization of aryl iodides to alkyl iodides, known as carboiodination. In the context of the Pd-catalyzed variant, the chapter explores the production of enantioenriched carboxamides through diastereoselective Pd-catalyzed carboiodination. It then discusses Ni-catalyzed reactions to generate oxindoles and an enantioselective variant employing a dual ligand system. Chapter 2 introduces readers to a Pd-catalyzed diastereoselective anion-capture cascade. It also examines diastereoselective Pd-catalyzed aryl cyanation to synthesize alkyl nitriles, a method that generates high yields of borylated chromans as a single diastereomer, andhighlights its synthetic utility. Lastly, Chapter 3 presents a Pd-catalyzed domino process harnessing carbopalladation, C-H activation and π-system insertion (benzynes and alkynes) to generate spirocycles. It also describes the mechanistic studies performed on these reactions.